{ "job_id": "33874dde-ef80-4155-8a7c-dbe7488cdc7e", "created_at": "2020-06-24T09:32:18.318894", "status": "SUCCESS", "result": [ { "biblio": { "filename": "33874dde-ef80-4155-8a7c-dbe7488cdc7e.html" }, "tables": [ { "caption": "Table 1 Crystallographic data for 1\u20134, 8, 9 and ppt", "heading": 0, "tde_table": [ [ "296.2", [ "T/K" ], [ "1" ] ], [ "296.2", [ "T/K" ], [ "2" ] ], [ "296.2", [ "T/K" ], [ "3" ] ], [ "296.2", [ "T/K" ], [ "4" ] ], [ "296.2", [ "T/K" ], [ "8" ] ], [ "296.2", [ "T/K" ], [ "ppt" ] ], [ "296.2", [ "T/K" ], [ "9" ] ], [ "296.2", [ "T/K" ], [ "14" ] ], [ "CuC10H8Cl2N2S2", [ "Formula" ], [ "1" ] ], [ "Cu2C20H16Cl4N4S4", [ "Formula" ], [ "2" ] ], [ "CuC10H8Br2N2S2", [ "Formula" ], [ "3" ] ], [ "CuC10H8ClN2S2", [ "Formula" ], [ "4" ] ], [ "CuC10H8BrN2S", [ "Formula" ], [ "8" ] ], [ "C10H8N2S", [ "Formula" ], [ "ppt" ] ], [ "CuC11H10Cl2N2S2", [ "Formula" ], [ "9" ] ], [ "CuC18H15F6N4PS3", [ "Formula" ], [ "14" ] ], [ "354.76", [ "M" ], [ "1" ] ], [ "709.52", [ "M" ], [ "2" ] ], [ "443.66", [ "M" ], [ "3" ] ], [ "319.31", [ "M" ], [ "4" ] ], [ "331.70", [ "M" ], [ "8" ] ], [ "188.25", [ "M" ], [ "ppt" ] ], [ "368.79", [ "M" ], [ "9" ] ], [ "592.03", [ "M" ], [ "14" ] ], [ "Trigonal", [ "Crystal system" ], [ "1" ] ], [ "Triclinic", [ "Crystal system" ], [ "2" ] ], [ "Monoclinic", [ "Crystal system" ], [ "3" ] ], [ "Monoclinic", [ "Crystal system" ], [ "4" ] ], [ "Triclinic", [ "Crystal system" ], [ "8" ] ], [ "Monoclinic", [ "Crystal system" ], [ "ppt" ] ], [ "Monoclinic", [ "Crystal system" ], [ "9" ] ], [ "Monoclinic", [ "Crystal system" ], [ "14" ] ], [ "P31\n(no. 144)", [ "Space group" ], [ "1" ] ], [ "P1\u0304\n(no. 2)", [ "Space group" ], [ "2" ] ], [ "C2/c\n(no. 15)", [ "Space group" ], [ "3" ] ], [ "P21/n (no. 14)", [ "Space group" ], [ "4" ] ], [ "P1\u0304\n(no. 2)", [ "Space group" ], [ "8" ] ], [ "P21\n(no. 4)", [ "Space group" ], [ "ppt" ] ], [ "P21/n\n(no. 14)", [ "Space group" ], [ "9" ] ], [ "P21/a (no. 14)", [ "Space group" ], [ "14" ] ], [ "8.3704(9)", [ "a/\u00c5" ], [ "1" ] ], [ "7.530(1)", [ "a/\u00c5" ], [ "2" ] ], [ "13.241(2)", [ "a/\u00c5" ], [ "3" ] ], [ "7.933(3)", [ "a/\u00c5" ], [ "4" ] ], [ "7.655(1)", [ "a/\u00c5" ], [ "8" ] ], [ "6.655(1)", [ "a/\u00c5" ], [ "ppt" ] ], [ "12.476(1)", [ "a/\u00c5" ], [ "9" ] ], [ "14.414(2)", [ "a/\u00c5" ], [ "14" ] ], [ "8.3704(9)", [ "b/\u00c5" ], [ "1" ] ], [ "8.2269(9)", [ "b/\u00c5" ], [ "2" ] ], [ "7.499(1)", [ "b/\u00c5" ], [ "3" ] ], [ "15.061(2)", [ "b/\u00c5" ], [ "4" ] ], [ "8.821(1)", [ "b/\u00c5" ], [ "8" ] ], [ "6.641(2)", [ "b/\u00c5" ], [ "ppt" ] ], [ "8.4932(9)", [ "b/\u00c5" ], [ "9" ] ], [ "10.132(2)", [ "b/\u00c5" ], [ "14" ] ], [ "16.774(2)", [ "c/\u00c5" ], [ "1" ] ], [ "11.618(1)", [ "c/\u00c5" ], [ "2" ] ], [ "14.093(1)", [ "c/\u00c5" ], [ "3" ] ], [ "10.383(2)", [ "c/\u00c5" ], [ "4" ] ], [ "9.4081(9)", [ "c/\u00c5" ], [ "8" ] ], [ "10.4614(7)", [ "c/\u00c5" ], [ "ppt" ] ], [ "13.1982(8)", [ "c/\u00c5" ], [ "9" ] ], [ "15.605(2)", [ "c/\u00c5" ], [ "14" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "1" ] ], [ "87.87(1)", [ "\u03b1/\u00b0" ], [ "2" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "3" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "4" ] ], [ "72.237(9)", [ "\u03b1/\u00b0" ], [ "8" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "ppt" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "9" ] ], [ "90", [ "\u03b1/\u00b0" ], [ "14" ] ], [ "90", [ "\u03b2/\u00b0" ], [ "1" ] ], [ "73.02(1)", [ "\u03b2/\u00b0" ], [ "2" ] ], [ "102.203(9)", [ "\u03b2/\u00b0" ], [ "3" ] ], [ "112.43(2)", [ "\u03b2/\u00b0" ], [ "4" ] ], [ "72.262(9)", [ "\u03b2/\u00b0" ], [ "8" ] ], [ "90.288(8)", [ "\u03b2/\u00b0" ], [ "ppt" ] ], [ "99.004(6)", [ "\u03b2/\u00b0" ], [ "9" ] ], [ "91.534(4)", [ "\u03b2/\u00b0" ], [ "14" ] ], [ "120", [ "\u03b3/\u00b0" ], [ "1" ] ], [ "71.86(1)", [ "\u03b3/\u00b0" ], [ "2" ] ], [ "90", [ "\u03b3/\u00b0" ], [ "3" ] ], [ "90", [ "\u03b3/\u00b0" ], [ "4" ] ], [ "67.494(10)", [ "\u03b3/\u00b0" ], [ "8" ] ], [ "90", [ "\u03b3/\u00b0" ], [ "ppt" ] ], [ "90", [ "\u03b3/\u00b0" ], [ "9" ] ], [ "90", [ "\u03b3/\u00b0" ], [ "14" ] ], [ "1017.8(2)", [ "U/\u00c53" ], [ "1" ] ], [ "653.0(2)", [ "U/\u00c53" ], [ "2" ] ], [ "1367.7(3)", [ "U/\u00c53" ], [ "3" ] ], [ "1146.6(4)", [ "U/\u00c53" ], [ "4" ] ], [ "546.0(1)", [ "U/\u00c53" ], [ "8" ] ], [ "456.3(1)", [ "U/\u00c53" ], [ "ppt" ] ], [ "1381.3(2)", [ "U/\u00c53" ], [ "9" ] ], [ "2278.4(6)", [ "U/\u00c53" ], [ "14" ] ], [ "3", [ "Z" ], [ "1" ] ], [ "2", [ "Z" ], [ "2" ] ], [ "1", [ "Z" ], [ "3" ] ], [ "4", [ "Z" ], [ "4" ] ], [ "2", [ "Z" ], [ "8" ] ], [ "2", [ "Z" ], [ "ppt" ] ], [ "4", [ "Z" ], [ "9" ] ], [ "4", [ "Z" ], [ "14" ] ], [ "8.586", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "1" ] ], [ "2.376", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "2" ] ], [ "7.740", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "3" ] ], [ "2.470", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "4" ] ], [ "5.825", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "8" ] ], [ "0.303", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "ppt" ] ], [ "2.250", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "9" ] ], [ "1.368", [ "\u03bc(Mo-K\u03b1)/mm\u22121" ], [ "14" ] ], [ "531.00", [ "F(000)" ], [ "1" ] ], [ "354.00", [ "F(000)" ], [ "2" ] ], [ "852.00", [ "F(000)" ], [ "3" ] ], [ "640.00", [ "F(000)" ], [ "4" ] ], [ "324.00", [ "F(000)" ], [ "8" ] ], [ "196.00", [ "F(000)" ], [ "ppt" ] ], [ "740.00", [ "F(000)" ], [ "9" ] ], [ "1188.00", [ "F(000)" ], [ "14" ] ], [ "2352", [ "Data collected" ], [ "1" ] ], [ "4059", [ "Data collected" ], [ "2" ] ], [ "2233", [ "Data collected" ], [ "3" ] ], [ "3686", [ "Data collected" ], [ "4" ] ], [ "3374", [ "Data collected" ], [ "8" ] ], [ "3104", [ "Data collected" ], [ "ppt" ] ], [ "4461", [ "Data collected" ], [ "9" ] ], [ "22495", [ "Data collected" ], [ "14" ] ], [ "2016 (0.018)", [ "Unique data (Rint)" ], [ "1" ] ], [ "3812 (0.007)", [ "Unique data (Rint)" ], [ "2" ] ], [ "2004 (0.018)", [ "Unique data (Rint)" ], [ "3" ] ], [ "3338 (0.018)", [ "Unique data (Rint)" ], [ "4" ] ], [ "3184 (0.007)", [ "Unique data (Rint)" ], [ "8" ] ], [ "2663 (0.016)", [ "Unique data (Rint)" ], [ "ppt" ] ], [ "4027 (0.032)", [ "Unique data (Rint)" ], [ "9" ] ], [ "5117 (0.040)", [ "Unique data (Rint)" ], [ "14" ] ], [ "2003", [ "Observed data [I > 2\u03c3(I)]" ], [ "1" ] ], [ "3310", [ "Observed data [I > 2\u03c3(I)]" ], [ "2" ] ], [ "1555", [ "Observed data [I > 2\u03c3(I)]" ], [ "3" ] ], [ "2440", [ "Observed data [I > 2\u03c3(I)]" ], [ "4" ] ], [ "2587", [ "Observed data [I > 2\u03c3(I)]" ], [ "8" ] ], [ "2433", [ "Observed data [I > 2\u03c3(I)]" ], [ "ppt" ] ], [ "2588", [ "Observed data [I > 2\u03c3(I)]" ], [ "9" ] ], [ "3700", [ "Observed data [I > 2\u03c3(I)]" ], [ "14" ] ], [ "0.0306", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "1" ] ], [ "0.0244", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "2" ] ], [ "0.0290", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "3" ] ], [ "0.0312", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "4" ] ], [ "0.0303", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "8" ] ], [ "0.0286", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "ppt" ] ], [ "0.0396", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "9" ] ], [ "0.0415", [ "Final R1\n[I > 2\u03c3(I)]" ], [ "14" ] ], [ "0.0857", [ "wR2" ], [ "1" ] ], [ "0.0631", [ "wR2" ], [ "2" ] ], [ "0.0700", [ "wR2" ], [ "3" ] ], [ "0.0687", [ "wR2" ], [ "4" ] ], [ "0.0737", [ "wR2" ], [ "8" ] ], [ "0.0828", [ "wR2" ], [ "ppt" ] ], [ "0.0978", [ "wR2" ], [ "9" ] ], [ "0.1054", [ "wR2" ], [ "14" ] ] ], "tde_raw_table": [ [ "Compound", "1", "2", "3", "4", "8", "ppt", "9", "14" ], [ "T/K", "296.2", "296.2", "296.2", "296.2", "296.2", "296.2", "296.2", "296.2" ], [ "Formula", "CuC10H8Cl2N2S2", "Cu2C20H16Cl4N4S4", "CuC10H8Br2N2S2", "CuC10H8ClN2S2", "CuC10H8BrN2S", "C10H8N2S", "CuC11H10Cl2N2S2", "CuC18H15F6N4PS3" ], [ "M", "354.76", "709.52", "443.66", "319.31", "331.70", "188.25", "368.79", "592.03" ], [ "Crystal system", "Trigonal", "Triclinic", "Monoclinic", "Monoclinic", "Triclinic", "Monoclinic", "Monoclinic", "Monoclinic" ], [ "Space group", "P31\n(no. 144)", "P1\u0304\n(no. 2)", "C2/c\n(no. 15)", "P21/n (no. 14)", "P1\u0304\n(no. 2)", "P21\n(no. 4)", "P21/n\n(no. 14)", "P21/a (no. 14)" ], [ "a/\u00c5", "8.3704(9)", "7.530(1)", "13.241(2)", "7.933(3)", "7.655(1)", "6.655(1)", "12.476(1)", "14.414(2)" ], [ "b/\u00c5", "8.3704(9)", "8.2269(9)", "7.499(1)", "15.061(2)", "8.821(1)", "6.641(2)", "8.4932(9)", "10.132(2)" ], [ "c/\u00c5", "16.774(2)", "11.618(1)", "14.093(1)", "10.383(2)", "9.4081(9)", "10.4614(7)", "13.1982(8)", "15.605(2)" ], [ "\u03b1/\u00b0", "90", "87.87(1)", "90", "90", "72.237(9)", "90", "90", "90" ], [ "\u03b2/\u00b0", "90", "73.02(1)", "102.203(9)", "112.43(2)", "72.262(9)", "90.288(8)", "99.004(6)", "91.534(4)" ], [ "\u03b3/\u00b0", "120", "71.86(1)", "90", "90", "67.494(10)", "90", "90", "90" ], [ "U/\u00c53", "1017.8(2)", "653.0(2)", "1367.7(3)", "1146.6(4)", "546.0(1)", "456.3(1)", "1381.3(2)", "2278.4(6)" ], [ "Z", "3", "2", "1", "4", "2", "2", "4", "4" ], [ "\u03bc(Mo-K\u03b1)/mm\u22121", "8.586", "2.376", "7.740", "2.470", "5.825", "0.303", "2.250", "1.368" ], [ "F(000)", "531.00", "354.00", "852.00", "640.00", "324.00", "196.00", "740.00", "1188.00" ], [ "Data collected", "2352", "4059", "2233", "3686", "3374", "3104", "4461", "22495" ], [ "Unique data (Rint)", "2016 (0.018)", "3812 (0.007)", "2004 (0.018)", "3338 (0.018)", "3184 (0.007)", "2663 (0.016)", "4027 (0.032)", "5117 (0.040)" ], [ "Observed data [I > 2\u03c3(I)]", "2003", "3310", "1555", "2440", "2587", "2433", "2588", "3700" ], [ "Final R1\n[I > 2\u03c3(I)]", "0.0306", "0.0244", "0.0290", "0.0312", "0.0303", "0.0286", "0.0396", "0.0415" ], [ "wR2", "0.0857", "0.0631", "0.0700", "0.0687", "0.0737", "0.0828", "0.0978", "0.1054" ] ] }, { "caption": "Table 2 Electrochemical data for [Cu(TPTM)(CH3CN)]PF6 and [CuBr(TPTM)]", "heading": [], "tde_table": [ [ "[Cu(TPTM)(CH3CN)]", [ "[Cu(TPTM)(CH3CN)]" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "\u22120.174 (0.089), 0.65 (0.100)", [ "CH2Cl2" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "\u22120.327 (0.064), 0.654 (pc)", [ "CH3CN" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "NoValue", [ "" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "[CuBr(TPTM)]", [ "[CuBr(TPTM)]" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "\u22120.691 (pa), 0.462 (0.063)", [ "CH2Cl2" ], [ "E/V (Epa\n\u2212\nEpc)" ] ], [ "\u22120.359 (0.065), 0.512 (0.084)", [ "CH3CN" ], [ "E/V (Epa\n\u2212\nEpc)" ] ] ], "tde_raw_table": [ [ "", "E/V (Epa\n\u2212\nEpc)" ], [ "[Cu(TPTM)(CH3CN)]", "[Cu(TPTM)(CH3CN)]" ], [ "CH2Cl2", "\u22120.174 (0.089), 0.65 (0.100)" ], [ "CH3CN", "\u22120.327 (0.064), 0.654 (pc)" ], [ "", "" ], [ "[CuBr(TPTM)]", "[CuBr(TPTM)]" ], [ "CH2Cl2", "\u22120.691 (pa), 0.462 (0.063)" ], [ "CH3CN", "\u22120.359 (0.065), 0.512 (0.084)" ] ] }, { "caption": "Table 3 S\u2013S Bond distances (\u00c5) and C\u2013S\u2013S\u2013C torsion angles (\u00b0) for Cu(II) complexes 1\u20133", "heading": 0, "tde_table": [ [ "S\u2013S", [ "S\u2013S" ], [ "2" ] ], [ "S\u2013S", [ "S\u2013S" ], [ "3" ] ], [ "2.024(1)", [ "2.031(2)" ], [ "2" ] ], [ "2.059(2)", [ "2.031(2)" ], [ "3" ] ], [ "2.047(1)", [ "" ], [ "2" ] ], [ "NoValue", [ "" ], [ "3" ] ], [ "C\u2013S\u2013S\u2013C", [ "C\u2013S\u2013S\u2013C" ], [ "2" ] ], [ "C\u2013S\u2013S\u2013C", [ "C\u2013S\u2013S\u2013C" ], [ "3" ] ], [ "71.1(2)", [ "71.1(2)" ], [ "2" ] ], [ "108.9(2)", [ "71.1(2)" ], [ "3" ] ] ], "tde_raw_table": [ [ "1", "2", "3" ], [ "S\u2013S", "S\u2013S", "S\u2013S" ], [ "2.031(2)", "2.024(1)", "2.059(2)" ], [ "", "2.047(1)", "" ], [ "", "", "" ], [ "C\u2013S\u2013S\u2013C", "C\u2013S\u2013S\u2013C", "C\u2013S\u2013S\u2013C" ], [ "71.1(2)", "71.1(2)", "108.9(2)" ], [ "", "81.3(2)", "" ] ] } ], "figures": [ { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s1.gif" ], "caption": "" }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s2.gif" ], "caption": "" }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s3.gif" ], "caption": "" }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s4.gif" ], "caption": "" }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s5.gif" ], "caption": "Ligand abbreviations: 3-mpds = 2,2\u2032-bis(3-methylpyridyl)disulfide; 6-mpds = 2,2\u2032-bis(6-methylpyridyl)disulfide (6-mpds); 6,3-mppt = 6-methyl-1-[2-(3-methyl)pyridyl]pyridinium-2-thiolate." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f1.gif" ], "caption": "CD spectra of resolved 6,3-mppt in 2-propanol." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-s6.gif" ], "caption": "" }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f2.gif" ], "caption": "Cyclic voltammetry of [Cu(CH3CN)(TPTM)]PF6\n(thin line) and [CuBr(TPTM)]\n(thick line) in (a) CH2Cl2 and (b) CH3CN." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f3.gif" ], "caption": "Absorption spectra of 14 in an electrolysis cell: (a) in CH2Cl2 before electrolysis (b) after electrolysis and measured in situ." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f4.gif" ], "caption": "Frozen glass ESR spectrum of [Cu(CH3CN)(TPTM)]PF6 in CH3CN \u2236 CH2Cl2\n\u2236 C3H7CN = 1 \u2236 1 \u2236 1." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f5.gif" ], "caption": "ORTEP drawing of 1 with a view along the 31 axis in the P31 space group (upper) and a stereoscopic view of the helicate. Part of the pyridine rings are removed for clarity." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f6.gif" ], "caption": "ORTEP drawing of 2, shown as a dimer." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f7.gif" ], "caption": "ORTEP drawing of [CuBr2(dpds)]\n(3)." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f8.gif" ], "caption": "ORTEP drawing of 8 along with a schematic representation." }, { "links": [ "http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210420m/b210420m-f9.gif" ], "caption": "ORTEP drawing of ppt." }, { "links": [ 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"[Cu(TPTM)(CH3CN)]PF6", "[CuCl2(\u03bc-dpds)2]n", "bis(2-pyridylthio)methane", "13C", "nitrogen", "dpds", "C18H15CuF6N4PS3", "ligandTris(2-pyridylthio)methane", "[Cu(\u03bc-Cl)(\u03bc-ppt)]n", "bis(3-methyl-2-pyridine)disulfide", "TPTMH", "2-dpds", "2,2\u2032-bis(3-methylpyridyl)disulfide", "TPTM", "CH", "hydrogen", "Cu(\u03bc-Cl)(\u03bc-dpds)", "CH2Cl2", "H", "N", "N", "CH", "dpds", "Cu", "Br", "chloride", "carbon", "acetonitrile", "dpds", "Cu\u2013N(acetonitrile)", "H", "CuBr", "C16H12BrCuN3S3", "3,3-mppt", "H", "H", "thiolate", "CH3CN", "dpds", "2,2\u2032-bis(6-methylpyridyl)disulfide", "C\u2013S", "Cu", "sulfur", "silica", "[CuI(\u03bc-Cl)(\u03bc-dpds)]n", "3-mpds", "N", "Cl", "H", "H", "acetonitrile", "silica", "ppt", "H", "[Cu(TPTM)(CH3CN)]PF6", "oxygen", "H", "C\u2013S", "[Cu(CH3CN)4]PF6", "TPTMH", "toluene", "Cu(1)", "ethanol", "copper", "ppt", "hydrogen", "C10H8N2S2CuCl2", "sulfur", "2,2\u2032-dipyridyldisulfide", "pyridine-2-thiol", "Cu(II)", "N", "Tris(2-pyridylthio)methane", "2,2\u2032-bis(6-methylpyridine)disulfide", "dpds", "pyridine", "BPTM", "CH2Cl2\u2013CH3CN", "[Cu(NCMe)4]+", "[Cu(Cl)2(\u03bc-BPTM)]n", "CuICl", "copper", "CuI", "BPTM", "BPTM", "C20H16Br4Cu4N4S4\u00b72CH2Cl2", "dpds", "CDCl3", "bis(2-pyridylthio)methane", "3-mpds", "Cu(II)", "H", "bromide", "TPTMH", "Cu(II)", "2-dpds", "C22H20Cu4I4N4S4", "C10H8N2S2CuCl2", "methanol", "CHIRALCEL OD", "CuBr", "bis[2-(2-pyridyl)ethyl](2-pyridyl)methylamine", "S\u2013S", "pyridine", "C\u2013S", "CH3", "disulfide", "CuCl2", "Cu(II)\u2013C(sp3)", "toluene", "CH2Cl2", "H", "H", "1H", "C11H10Br2CuN2S2", "CuBr2", "glassy-carbon-disk", "CuCl2\n[CuCl2(BPTM)]n", "C10H8N2S2CuBr", "CH3CN", "methanol", "[Cu(\u03bc-Br)(dpds)]2", "2H", "copper", "Cu", "CuBr(TPTM)", "C\u2013N", "[Cu(CH3CN)(TPTM)]PF6", "CuBr2(dpds)", "pyridinium nitrogen", "Cu(I)", "CuCl2(dpds)", "C10H8N2S2CuCl", "dpds", "Cu(II)", "KBr", "N", "CuBr(TPTM)", "CH", "pyt", "disulfide", "[CuCl2(\u03bc-dpds)2]n", "methanol", "C\u22efC", "6-methyl-1-[2-(3-methyl)pyridyl]pyridinium-2-thiolate", "sulfur", "Cu(II)", "pyridine-2-thiolate", "sulfur", "Cu\u2013S", "CuBr2", "S\u2013S", "dichloromethane", "Cu(I)", "Methanol", "dpds", "TPTMH", "[CuCl2(\u03bc-dpds)2]n", "[Cu(TPTM)(CH3CN)]PF6", "Cl\u2212", "chloride", "N", "methanol", "Sulfur", "copper" ], "issue": "10", "pages": "", "title": "Design and synthesis of copper complexes of novel ligands based on the pyridine thiolate group", "volume": "0", "authors": [ "Isamu Kinoshita", "L. James Wright", "Sachiko Kubo", "Kentaro Kimura", "Akio Sakata", "Toshihiro Yano", "Riichi Miyamoto", "Takanori Nishioka", "Kiyoshi Isobe", "Isamu Kinoshita", "L. James Wright", "Sachiko Kubo", "Kentaro Kimura", "Akio Sakata", "Toshihiro Yano", "Riichi Miyamoto", "Takanori Nishioka", "Kiyoshi Isobe" ], "journal": "Dalton Transactions", "pdf_url": "http://pubs.rsc.org/en/Content/ArticlePDF/2003/DT/B210420M", "html_url": "http://pubs.rsc.org/en/Content/ArticleLanding/2003/DT/B210420M", "lastpage": "2003", "copyright": "", "firstpage": "1993", "publisher": "Royal Society of Chemistry", "definitions": [ { "end": 17, "start": 13, "tokens": [ [ "Akio", "NNP" ], [ "Sakata", "NNP" ], [ ",", "," ], [ "Toshihiro", "NNP" ] ], "specifier": "Toshihiro", "definition": "Akio Sakata" }, { "end": 23, "start": 19, "tokens": [ [ "Riichi", "NNP" ], [ "Miyamoto", "NNP" ], [ ",", "," ], [ "Takanori", "NNP" ] ], "specifier": "Takanori", "definition": "Riichi Miyamoto" }, { "end": 25, "start": 23, "tokens": [ [ "including", "VBG" ], [ "[CuCl2(\u03bc-dpds)]", "B-CM" ] ], "specifier": "[CuCl2(\u03bc-dpds)]", "definition": "including" }, { "end": 16, "start": 10, 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Johnson" }, { "end": 32, "start": 28, "tokens": [ [ "Oak", "NNP" ], [ "Ridge", "NNP" ], [ ",", "," ], [ "TN", "NNP" ] ], "specifier": "TN", "definition": "Oak Ridge" } ], "published_date": "2003-05-15", "abbreviation_definitions": [ { "long_form": "2,2\u2032-dipyridyldisulfide", "abbreviation": "dpds" }, { "long_form": "bis(2-pyridylthio)methane", "abbreviation": "BPTM" }, { "long_form": "tris(2-pyridylthio)methane", "abbreviation": "TPTMH" }, { "long_form": "pyridine-2-thiolate", "abbreviation": "pyt" }, { "long_form": "5-methylpyridine-2-thiolate", "abbreviation": "5mpyt" }, { "long_form": "1-(2-pyridyl)pyridinium-2-thiolate", "abbreviation": "ppt" }, { "long_form": "bis(2-pyridylthio)methane", "abbreviation": "BPTM" }, { "long_form": "149.44 ( 6-py ) , 136.02", "abbreviation": "4-py" }, { "long_form": "122.50 ( 3-py ) , 119.71", "abbreviation": "5-py" }, { "long_form": "Tris(2-pyridylthio)methane", "abbreviation": "TPTM" }, { "long_form": "136.31 ( 4-py ) , 122.20", "abbreviation": "3-py" }, { "long_form": "6-methyl-1-[2-(3-methyl)pyridyl]pyridinium-2-thiolate", "abbreviation": "6,3-mppt" }, { "long_form": "2,2\u2032-bis(3-methylpyridyl)disulfide", "abbreviation": "3-mpds" }, { "long_form": "2,2\u2032-bis(6-methylpyridyl)disulfide", "abbreviation": "6-mpds" }, { "long_form": "2,2\u2032-dipyridyldisulfide", "abbreviation": "dpds" }, { "long_form": "1-(2-pyridyl)pyridinium-2-thiolate", "abbreviation": "ppt" }, { "long_form": "1-(2-pyridyl)pyridinium-2-thiolate", "abbreviation": "ppt" }, { "long_form": "2,2\u2032-bis(6-methylpyridine)disulfide", "abbreviation": "6-mpds" }, { "long_form": "2,2\u2032-bis(3-methylpyridine)disulfide", "abbreviation": "3-mpds" }, { "long_form": "2,2\u2032-bis(3-methylpyridyl)disulfide", "abbreviation": "3-mpds" }, { "long_form": "2,2\u2032-bis(6-methylpyridyl)disulfide", "abbreviation": "6-mpds" }, { "long_form": "6-methyl-1-[2-(3-methyl)pyridyl]pyridinium-2-thiolate", "abbreviation": "6,3-mppt" }, { "long_form": "2,2\u2032-bis(3-methylpyridyl)disulfide", "abbreviation": "3-mpds" }, { "long_form": "2,2\u2032-bis(6-methylpyridyl)disulfide", "abbreviation": "6-mpds" }, { "long_form": "6-methyl-1-[2-(3-methyl)pyridyl]pyridinium-2-thiolate", "abbreviation": "6,3-mppt" }, { "long_form": "2,2\u2032-bis(6-methylpyridyl)disulfide", "abbreviation": "6-mpds" }, { "long_form": "the new ligandTris(2-pyridylthio)methane", "abbreviation": "TPTMH" }, { "long_form": "2,2\u2032-dipyridyldisulfide", "abbreviation": "2-dpds" }, { "long_form": "1-(2-pyridyl)pyridinium-2-thiolate", "abbreviation": "ppt" }, { "long_form": "bis(2-pyridylthio)methane", "abbreviation": "BPTM" }, { "long_form": "2,2\u2032-dipyridyldisulfide", "abbreviation": "dpds" }, { "long_form": "tris(2-pyridylthio)methane", "abbreviation": "TPTMH" } ] } } ] }