9ddb19ce-4412-4989-9420-7bd7014865292020-06-24T09:08:23.023328SUCCESS- 9ddb19ce-4412-4989-9420-7bd701486529.html
- Table 1 Crystallographic data for Sc complexes0
- C14H26Cl13N2O5Sb2Sc
- Formula
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- C12H24Cl6FeO6Sc
- Formula
- [ScCl2(18-crown-6)][FeCl4]
- C12H30Cl3O9Sc
- Formula
- [ScCl3(H2O)3]·18-crown-6
- C16H48N5NaO32Sc2
- Formula
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- C8H30N4O24Sc2
- Formula
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- C16H36N3O19Sc
- Formula
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 1051.68
- M
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 577.82
- M
- [ScCl2(18-crown-6)][FeCl4]
- 469.67
- M
- [ScCl3(H2O)3]·18-crown-6
- 935.50
- M
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 656.28
- M
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 619.44
- M
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- Orthorhombic
- Crystal system
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- Orthorhombic
- Crystal system
- [ScCl2(18-crown-6)][FeCl4]
- Orthorhombic
- Crystal system
- [ScCl3(H2O)3]·18-crown-6
- Triclinic
- Crystal system
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- Triclinic
- Crystal system
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- Orthorhombic
- Crystal system
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- Pbca
(no. 61)
- Space group
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- Pna21
(no. 33)
- Space group
- [ScCl2(18-crown-6)][FeCl4]
- Pbcn
(no. 60)
- Space group
- [ScCl3(H2O)3]·18-crown-6
- P1̄
(no. 2)
- Space group
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- P1̄
(no. 2)
- Space group
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- P21212 (no. 18)
- Space group
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 21.209(2)
- a/Å
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 19.2026(15)
- a/Å
- [ScCl2(18-crown-6)][FeCl4]
- 10.7210(10)
- a/Å
- [ScCl3(H2O)3]·18-crown-6
- 8.7342(10)
- a/Å
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 7.5712(15)
- a/Å
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 11.6362(15)
- a/Å
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 13.4224(10)
- b/Å
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 11.2156(10)
- b/Å
- [ScCl2(18-crown-6)][FeCl4]
- 14.8569(15)
- b/Å
- [ScCl3(H2O)3]·18-crown-6
- 13.4735(15)
- b/Å
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 9.2350(15)
- b/Å
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 13.432(3)
- b/Å
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 24.800(2)
- c/Å
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 21.0990(15)
- c/Å
- [ScCl2(18-crown-6)][FeCl4]
- 13.2776(15)
- c/Å
- [ScCl3(H2O)3]·18-crown-6
- 16.842(3)
- c/Å
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 9.862(3)
- c/Å
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 8.7311(10)
- c/Å
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 90.0
- α/°
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 90.0
- α/°
- [ScCl2(18-crown-6)][FeCl4]
- 90.0
- α/°
- [ScCl3(H2O)3]·18-crown-6
- 100.341(4)
- α/°
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 85.497(7)
- α/°
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 90.0
- α/°
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 90.0
- β/°
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 90.0
- β/°
- [ScCl2(18-crown-6)][FeCl4]
- 90.0
- β/°
- [ScCl3(H2O)3]·18-crown-6
- 98.989(4)
- β/°
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 84.869(8)
- β/°
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 90.0
- β/°
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 90.0
- γ/°
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 90.0
- γ/°
- [ScCl2(18-crown-6)][FeCl4]
- 90.0
- γ/°
- [ScCl3(H2O)3]·18-crown-6
- 93.665(7)
- γ/°
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 69.545(15)
- γ/°
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 90.0
- γ/°
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 7060.0(10)
- U/Å3
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 4544.1(6)
- U/Å3
- [ScCl2(18-crown-6)][FeCl4]
- 2114.9(4)
- U/Å3
- [ScCl3(H2O)3]·18-crown-6
- 1917.2(4)
- U/Å3
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 642.7(2)
- U/Å3
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 1364.7(3)
- U/Å3
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 1.979
- Dcalc/g cm−3
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 1.689
- Dcalc/g cm−3
- [ScCl2(18-crown-6)][FeCl4]
- 1.475
- Dcalc/g cm−3
- [ScCl3(H2O)3]·18-crown-6
- 1.621
- Dcalc/g cm−3
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 1.696
- Dcalc/g cm−3
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 1.507
- Dcalc/g cm−3
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 8
- Z
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 8
- Z
- [ScCl2(18-crown-6)][FeCl4]
- 4
- Z
- [ScCl3(H2O)3]·18-crown-6
- 2
- Z
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 1
- Z
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 2
- Z
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 4064
- F(000)
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 2344
- F(000)
- [ScCl2(18-crown-6)][FeCl4]
- 984
- F(000)
- [ScCl3(H2O)3]·18-crown-6
- 976
- F(000)
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 340
- F(000)
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 652
- F(000)
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.36 × 0.24 × 0.16
- Crystal size/mm
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.26 × 0.26 × 0.20
- Crystal size/mm
- [ScCl2(18-crown-6)][FeCl4]
- 0.30 × 0.26 × 0.20
- Crystal size/mm
- [ScCl3(H2O)3]·18-crown-6
- 0.32 × 0.30 × 0.26
- Crystal size/mm
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.26 × 0.20 × 0.10
- Crystal size/mm
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.28 × 0.20 × 0.18
- Crystal size/mm
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 38521
- No. reflections measured
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 33479
- No. reflections measured
- [ScCl2(18-crown-6)][FeCl4]
- 17374
- No. reflections measured
- [ScCl3(H2O)3]·18-crown-6
- 26054
- No. reflections measured
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 8198
- No. reflections measured
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 9719
- No. reflections measured
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 8017 (0.107)
- No. unique reflns (Rint)
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 10116 (0.060)
- No. unique reflns (Rint)
- [ScCl2(18-crown-6)][FeCl4]
- 2415(0.073)
- No. unique reflns (Rint)
- [ScCl3(H2O)3]·18-crown-6
- 6636 (0.058)
- No. unique reflns (Rint)
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 2801 (0.085)
- No. unique reflns (Rint)
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 3109 (0.050)
- No. unique reflns (Rint)
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 55.0
- 2θ(max)/°
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 55.0
- 2θ(max)/°
- [ScCl2(18-crown-6)][FeCl4]
- 54.9
- 2θ(max)/°
- [ScCl3(H2O)3]·18-crown-6
- 50.0
- 2θ(max)/°
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 54.9
- 2θ(max)/°
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 54.9
- 2θ(max)/°
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.8822, 0.7992
- Max., min. transmission
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.8875, 0.8157
- Max., min. transmission
- [ScCl2(18-crown-6)][FeCl4]
- 0.9492, 0.7854
- Max., min. transmission
- [ScCl3(H2O)3]·18-crown-6
- 0.8954, 0.8798
- Max., min. transmission
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.9230, 0.8746
- Max., min. transmission
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.8857, 0.8521
- Max., min. transmission
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 8017
- No. of data in refinement
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 10116
- No. of data in refinement
- [ScCl2(18-crown-6)][FeCl4]
- 2415
- No. of data in refinement
- [ScCl3(H2O)3]·18-crown-6
- 6636
- No. of data in refinement
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 2801
- No. of data in refinement
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 3109
- No. of data in refinement
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 335/0
- No. params/restraints
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 470/1
- No. params/restraints
- [ScCl2(18-crown-6)][FeCl4]
- 125/3
- No. params/restraints
- [ScCl3(H2O)3]·18-crown-6
- 493/3
- No. params/restraints
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 191/6
- No. params/restraints
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 185/2
- No. params/restraints
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- n.a.
- Flack parameter
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.09(1)
- Flack parameter
- [ScCl2(18-crown-6)][FeCl4]
- n.a.
- Flack parameter
- [ScCl3(H2O)3]·18-crown-6
- n.a.
- Flack parameter
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- n.a.
- Flack parameter
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.00(3)
- Flack parameter
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 27.19
- μ/cm−1
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 16.67
- μ/cm−1
- [ScCl2(18-crown-6)][FeCl4]
- 7.65
- μ/cm−1
- [ScCl3(H2O)3]·18-crown-6
- 4.79
- μ/cm−1
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 6.36
- μ/cm−1
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 3.58
- μ/cm−1
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.952
- S
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.992
- S
- [ScCl2(18-crown-6)][FeCl4]
- 1.036
- S
- [ScCl3(H2O)3]·18-crown-6
- 1.019
- S
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 1.027
- S
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 1.015
- S
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.003
- Max. shift/e.s.d.
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.001
- Max. shift/e.s.d.
- [ScCl2(18-crown-6)][FeCl4]
- 0.001
- Max. shift/e.s.d.
- [ScCl3(H2O)3]·18-crown-6
- 0.001
- Max. shift/e.s.d.
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.000
- Max. shift/e.s.d.
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.000
- Max. shift/e.s.d.
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- −0.97 to +0.94
- Residual e-density/e Å−3
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- −0.56 to +0.44
- Residual e-density/e Å−3
- [ScCl2(18-crown-6)][FeCl4]
- –0.39 to +0.37
- Residual e-density/e Å−3
- [ScCl3(H2O)3]·18-crown-6
- −0.56 to +1.01
- Residual e-density/e Å−3
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- −0.47 to +0.34
- Residual e-density/e Å−3
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- −0.37 to +0.22
- Residual e-density/e Å−3
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.042 ( 4920 refs)
- R
(I > 2σ(I))
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.039 (7859 refs)
- R
(I > 2σ(I))
- [ScCl2(18-crown-6)][FeCl4]
- 0.038 (1767 refs)
- R
(I > 2σ(I))
- [ScCl3(H2O)3]·18-crown-6
- 0.050 (4294 refs)
- R
(I > 2σ(I))
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.041 (2053 refs)
- R
(I > 2σ(I))
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.041 (2506 refs)
- R
(I > 2σ(I))
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.098
- R
(all data)
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.065
- R
(all data)
- [ScCl2(18-crown-6)][FeCl4]
- 0.062
- R
(all data)
- [ScCl3(H2O)3]·18-crown-6
- 0.090
- R
(all data)
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.069
- R
(all data)
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.060
- R
(all data)
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 0.086
- wR2
(all data)
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- 0.080
- wR2
(all data)
- [ScCl2(18-crown-6)][FeCl4]
- 0.092
- wR2
(all data)
- [ScCl3(H2O)3]·18-crown-6
- 0.145
- wR2
(all data)
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- 0.098
- wR2
(all data)
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 0.088
- wR2
(all data)
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- Compound
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- [ScCl2(18-crown-6)][FeCl4]
- [ScCl3(H2O)3]·18-crown-6
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- Formula
- C14H26Cl13N2O5Sb2Sc
- C12H24Cl6FeO6Sc
- C12H30Cl3O9Sc
- C16H48N5NaO32Sc2
- C8H30N4O24Sc2
- C16H36N3O19Sc
- M
- 1051.68
- 577.82
- 469.67
- 935.50
- 656.28
- 619.44
- Crystal system
- Orthorhombic
- Orthorhombic
- Orthorhombic
- Triclinic
- Triclinic
- Orthorhombic
- Space group
- Pbca
(no. 61)
- Pna21
(no. 33)
- Pbcn
(no. 60)
- P1̄
(no. 2)
- P1̄
(no. 2)
- P21212 (no. 18)
- a/Å
- 21.209(2)
- 19.2026(15)
- 10.7210(10)
- 8.7342(10)
- 7.5712(15)
- 11.6362(15)
- b/Å
- 13.4224(10)
- 11.2156(10)
- 14.8569(15)
- 13.4735(15)
- 9.2350(15)
- 13.432(3)
- c/Å
- 24.800(2)
- 21.0990(15)
- 13.2776(15)
- 16.842(3)
- 9.862(3)
- 8.7311(10)
- α/°
- 90.0
- 90.0
- 90.0
- 100.341(4)
- 85.497(7)
- 90.0
- β/°
- 90.0
- 90.0
- 90.0
- 98.989(4)
- 84.869(8)
- 90.0
- γ/°
- 90.0
- 90.0
- 90.0
- 93.665(7)
- 69.545(15)
- 90.0
- U/Å3
- 7060.0(10)
- 4544.1(6)
- 2114.9(4)
- 1917.2(4)
- 642.7(2)
- 1364.7(3)
- Dcalc/g cm−3
- 1.979
- 1.689
- 1.475
- 1.621
- 1.696
- 1.507
- Z
- 8
- 8
- 4
- 2
- 1
- 2
- F(000)
- 4064
- 2344
- 984
- 976
- 340
- 652
- Crystal size/mm
- 0.36 × 0.24 × 0.16
- 0.26 × 0.26 × 0.20
- 0.30 × 0.26 × 0.20
- 0.32 × 0.30 × 0.26
- 0.26 × 0.20 × 0.10
- 0.28 × 0.20 × 0.18
- No. reflections measured
- 38521
- 33479
- 17374
- 26054
- 8198
- 9719
- No. unique reflns (Rint)
- 8017 (0.107)
- 10116 (0.060)
- 2415(0.073)
- 6636 (0.058)
- 2801 (0.085)
- 3109 (0.050)
- 2θ(max)/°
- 55.0
- 55.0
- 54.9
- 50.0
- 54.9
- 54.9
- Max., min. transmission
- 0.8822, 0.7992
- 0.8875, 0.8157
- 0.9492, 0.7854
- 0.8954, 0.8798
- 0.9230, 0.8746
- 0.8857, 0.8521
- No. of data in refinement
- 8017
- 10116
- 2415
- 6636
- 2801
- 3109
- No. params/restraints
- 335/0
- 470/1
- 125/3
- 493/3
- 191/6
- 185/2
- Flack parameter
- n.a.
- 0.09(1)
- n.a.
- n.a.
- n.a.
- 0.00(3)
- μ/cm−1
- 27.19
- 16.67
- 7.65
- 4.79
- 6.36
- 3.58
- S
- 0.952
- 0.992
- 1.036
- 1.019
- 1.027
- 1.015
- Max. shift/e.s.d.
- 0.003
- 0.001
- 0.001
- 0.001
- 0.000
- 0.000
- Residual e-density/e Å−3
- −0.97 to +0.94
- −0.56 to +0.44
- –0.39 to +0.37
- −0.56 to +1.01
- −0.47 to +0.34
- −0.37 to +0.22
- R
(I > 2σ(I))
- 0.042 ( 4920 refs)
- 0.039 (7859 refs)
- 0.038 (1767 refs)
- 0.050 (4294 refs)
- 0.041 (2053 refs)
- 0.041 (2506 refs)
- R
(all data)
- 0.098
- 0.065
- 0.062
- 0.090
- 0.069
- 0.060
- wR2
(all data)
- 0.086
- 0.080
- 0.092
- 0.145
- 0.098
- 0.088
- Table 2 Selected bond lengths (Å) and angles (°) for [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN0
- 2.135(3)
- Sc(1)–O(1)
- 2.361(2)
- Sc(1)–O(4)
- Sc(1)–O(1)
- Sc(1)–N(1)
- 2.154(3)
- Sc(1)–O(1)
- 2.272(4)
- 2.155(3)
- Sc(1)–O(2)
- 2.361(2)
- Sc(1)–O(5)
- Sc(1)–O(2)
- Sc(1)–N(1)
- 2.176(3)
- Sc(1)–O(2)
- 2.272(4)
- 2.164(3)
- Sc(1)–O(3)
- 2.361(2)
- NoValue
- Sc(1)–O(3)
- Sc(1)–N(1)
- NoValue
- Sc(1)–O(3)
- 2.272(4)
- 1.444(6)–1.469(6)
- C–O
- 2.361(2)
- C–C (ring)
- C–O
- Sc(1)–N(1)
- 1.477(7)–1.501(7)
- C–O
- 2.272(4)
- 2.356(1)–2.382(1)
- Sb(1)–Cl
- 2.361(2)
- NoValue
- Sb(1)–Cl
- Sc(1)–N(1)
- NoValue
- Sb(1)–Cl
- 2.272(4)
- 2.356(1)–2.372(1)
- Sb(2)–Cl
- 2.361(2)
- NoValue
- Sb(2)–Cl
- Sc(1)–N(1)
- NoValue
- Sb(2)–Cl
- 2.272(4)
- 71.2(1)
- O(1)–Sc(1)–O(2)
- 2.361(2)
- O(5)–Sc(1)–O(1)
- O(1)–Sc(1)–O(2)
- Sc(1)–N(1)
- 71.7(1)
- O(1)–Sc(1)–O(2)
- 2.272(4)
- 72.1(1)
- O(2)–Sc(1)–O(3)
- 2.361(2)
- N(1)–Sc(1)–Cl(1)
- O(2)–Sc(1)–O(3)
- Sc(1)–N(1)
- 178.2(1)
- O(2)–Sc(1)–O(3)
- 2.272(4)
- 71.5(1)
- O(3)–Sc(1)–O(4)
- 2.361(2)
- O(5)–Sc(1)–Cl(1)
- O(3)–Sc(1)–O(4)
- Sc(1)–N(1)
- 92.14(9)
- O(3)–Sc(1)–O(4)
- 2.272(4)
- 72.5(1)
- O(4)–Sc(1)–O(5)
- 2.361(2)
- O(4)–Sc(1)–Cl(1)
- O(4)–Sc(1)–O(5)
- Sc(1)–N(1)
- 95.7(1)
- O(4)–Sc(1)–O(5)
- 2.272(4)
- Sc(1)–Cl(1)
- 2.361(2)
- Sc(1)–N(1)
- 2.272(4)
- Sc(1)–O(1)
- 2.135(3)
- Sc(1)–O(4)
- 2.154(3)
- Sc(1)–O(2)
- 2.155(3)
- Sc(1)–O(5)
- 2.176(3)
- Sc(1)–O(3)
- 2.164(3)
- C–O
- 1.444(6)–1.469(6)
- C–C (ring)
- 1.477(7)–1.501(7)
- Sb(1)–Cl
- 2.356(1)–2.382(1)
- Sb(2)–Cl
- 2.356(1)–2.372(1)
- O(1)–Sc(1)–O(2)
- 71.2(1)
- O(5)–Sc(1)–O(1)
- 71.7(1)
- O(2)–Sc(1)–O(3)
- 72.1(1)
- N(1)–Sc(1)–Cl(1)
- 178.2(1)
- O(3)–Sc(1)–O(4)
- 71.5(1)
- O(5)–Sc(1)–Cl(1)
- 92.14(9)
- O(4)–Sc(1)–O(5)
- 72.5(1)
- O(4)–Sc(1)–Cl(1)
- 95.7(1)
- Table 3 Selected bond lengths (Å) and angles (°) for [ScCl2(18-crown-6)][FeCl4]0
- 2.195(2)
- Sc(1)–O(1)
- 2.435(1)
- Sc(1)–O(5)
- Sc(1)–O(1)
- Sc(1)–Cl(2)
- 2.243(2)
- Sc(1)–O(1)
- 2.413(1)
- 2.192(2)
- Sc(1)–O(2)
- 2.435(1)
- Sc(1)–O(6)
- Sc(1)–O(2)
- Sc(1)–Cl(2)
- 2.210(2)
- Sc(1)–O(2)
- 2.413(1)
- 2.230(2)
- Sc(1)–O(3)
- 2.435(1)
- NoValue
- Sc(1)–O(3)
- Sc(1)–Cl(2)
- NoValue
- Sc(1)–O(3)
- 2.413(1)
- 2.425(1)
- Sc(2)–Cl(3)
- 2.435(1)
- Sc(2)–Cl(4)
- Sc(2)–Cl(3)
- Sc(1)–Cl(2)
- 2.402(1)
- Sc(2)–Cl(3)
- 2.413(1)
- 2.264(2)
- Sc(2)–O(7)
- 2.435(1)
- Sc(2)–O(11)
- Sc(2)–O(7)
- Sc(1)–Cl(2)
- 2.213(2)
- Sc(2)–O(7)
- 2.413(1)
- 2.216(2)
- Sc(2)–O(9)
- 2.435(1)
- Sc(2)–O(12)
- Sc(2)–O(9)
- Sc(1)–Cl(2)
- 2.202(2)
- Sc(2)–O(9)
- 2.413(1)
- 2.200(2)
- Sc(2)–O(10)
- 2.435(1)
- NoValue
- Sc(2)–O(10)
- Sc(1)–Cl(2)
- NoValue
- Sc(2)–O(10)
- 2.413(1)
- 1.417(4)–1.473(4)
- C–O
- 2.435(1)
- C–C
- C–O
- Sc(1)–Cl(2)
- 1.483(5)–1.503(5)
- C–O
- 2.413(1)
- 2.179(1)–2.202(1)
- Fe(1)–Cl
- 2.435(1)
- NoValue
- Fe(1)–Cl
- Sc(1)–Cl(2)
- NoValue
- Fe(1)–Cl
- 2.413(1)
- 2.184(1)–2.202(1)
- Fe(2)–Cl
- 2.435(1)
- NoValue
- Fe(2)–Cl
- Sc(1)–Cl(2)
- NoValue
- Fe(2)–Cl
- 2.413(1)
- 70.76(9)
- O(1)–Sc(1)–O(2)
- 2.435(1)
- O(6)–Sc(1)–O(1)
- O(1)–Sc(1)–O(2)
- Sc(1)–Cl(2)
- 69.60(9)
- O(1)–Sc(1)–O(2)
- 2.413(1)
- 71.68(8)
- O(2)–Sc(1)–O(3)
- 2.435(1)
- Cl(1)–Sc(1)–Cl(2)
- O(2)–Sc(1)–O(3)
- Sc(1)–Cl(2)
- 177.96(5)
- O(2)–Sc(1)–O(3)
- 2.413(1)
- 77.50(9)
- O(3)–Sc(1)–O(5)
- 2.435(1)
- O(1)–Sc(1)–Cl(1)
- O(3)–Sc(1)–O(5)
- Sc(1)–Cl(2)
- 85.58(7)
- O(3)–Sc(1)–O(5)
- 2.413(1)
- 71.72(8)
- O(5)–Sc(1)–O(6)
- 2.435(1)
- O(3)–Sc(1)–Cl(1)
- O(5)–Sc(1)–O(6)
- Sc(1)–Cl(2)
- 95.50(7)
- O(5)–Sc(1)–O(6)
- 2.413(1)
- 77.85(9)
- O(7)–Sc(2)–O(9)
- 2.435(1)
- O(12)–Sc(2)-O(7)
- O(7)–Sc(2)–O(9)
- Sc(1)–Cl(2)
- 72.28(9)
- O(7)–Sc(2)–O(9)
- 2.413(1)
- 70.66(8)
- O(9)–Sc(2)–O(10)
- 2.435(1)
- Cl(3)–Sc(2)–Cl(4)
- O(9)–Sc(2)–O(10)
- Sc(1)–Cl(2)
- 176.35(4)
- O(9)–Sc(2)–O(10)
- 2.413(1)
- 71.11(9)
- O(10)–Sc(2)–O(11)
- 2.435(1)
- O(11)–Sc(2)–Cl(3)
- O(10)–Sc(2)–O(11)
- Sc(1)–Cl(2)
- 86.47(7)
- O(10)–Sc(2)–O(11)
- 2.413(1)
- 68.96(9)
- O(11)–Sc(2)–O(12)
- 2.435(1)
- O(9)–Sc(2)–Cl(3)
- O(11)–Sc(2)–O(12)
- Sc(1)–Cl(2)
- 95.12(7)
- O(11)–Sc(2)–O(12)
- 2.413(1)
- Sc(1)–Cl(1)
- 2.435(1)
- Sc(1)–Cl(2)
- 2.413(1)
- Sc(1)–O(1)
- 2.195(2)
- Sc(1)–O(5)
- 2.243(2)
- Sc(1)–O(2)
- 2.192(2)
- Sc(1)–O(6)
- 2.210(2)
- Sc(1)–O(3)
- 2.230(2)
- Sc(2)–Cl(3)
- 2.425(1)
- Sc(2)–Cl(4)
- 2.402(1)
- Sc(2)–O(7)
- 2.264(2)
- Sc(2)–O(11)
- 2.213(2)
- Sc(2)–O(9)
- 2.216(2)
- Sc(2)–O(12)
- 2.202(2)
- Sc(2)–O(10)
- 2.200(2)
- C–O
- 1.417(4)–1.473(4)
- C–C
- 1.483(5)–1.503(5)
- Fe(1)–Cl
- 2.179(1)–2.202(1)
- Fe(2)–Cl
- 2.184(1)–2.202(1)
- O(1)–Sc(1)–O(2)
- 70.76(9)
- O(6)–Sc(1)–O(1)
- 69.60(9)
- O(2)–Sc(1)–O(3)
- 71.68(8)
- Cl(1)–Sc(1)–Cl(2)
- 177.96(5)
- O(3)–Sc(1)–O(5)
- 77.50(9)
- O(1)–Sc(1)–Cl(1)
- 85.58(7)
- O(5)–Sc(1)–O(6)
- 71.72(8)
- O(3)–Sc(1)–Cl(1)
- 95.50(7)
- O(7)–Sc(2)–O(9)
- 77.85(9)
- O(12)–Sc(2)-O(7)
- 72.28(9)
- O(9)–Sc(2)–O(10)
- 70.66(8)
- Cl(3)–Sc(2)–Cl(4)
- 176.35(4)
- O(10)–Sc(2)–O(11)
- 71.11(9)
- O(11)–Sc(2)–Cl(3)
- 86.47(7)
- O(11)–Sc(2)–O(12)
- 68.96(9)
- O(9)–Sc(2)–Cl(3)
- 95.12(7)
- Table 4 Selected bond lengths (Å) and angles (°) for [ScCl3(H2O)3]·18-crown-60
- 2.142(1)
- Sc(1)–O(5)
- 2.177(2)
- Sc(1)–Cl(2)
- Sc(1)–O(5)
- Sc(1)–Cl(1)
- 2.4267(8)
- Sc(1)–O(5)
- 2.4403(6)
- 1.419(3)–1.446(3)
- C–O
- 2.177(2)
- C–C
- C–O
- Sc(1)–Cl(1)
- 1.441(3)–1.484(4)
- C–O
- 2.4403(6)
- 81.89(4)
- O(4)–Sc(1)–O(5)
- 2.177(2)
- O(4)–Sc(1)–Cl(1)
- O(4)–Sc(1)–O(5)
- Sc(1)–Cl(1)
- 88.14(2)
- O(4)–Sc(1)–O(5)
- 2.4403(6)
- 163.78(8)
- O(5)–Sc(1)–O(5i)
- 2.177(2)
- O(4)–Sc(1)–Cl(2)
- O(5)–Sc(1)–O(5i)
- Sc(1)–Cl(1)
- 180.00
- O(5)–Sc(1)–O(5i)
- 2.4403(6)
- 91.86(2)
- Cl(1)–Sc(1)–Cl(2)
- 2.177(2)
- O(5)–Sc(1)–Cl(1)
- Cl(1)–Sc(1)–Cl(2)
- Sc(1)–Cl(1)
- 89.79(5)
- Cl(1)–Sc(1)–Cl(2)
- 2.4403(6)
- 176.27(3)
- Cl(1)–Sc(1)–Cl(1i)
- 2.177(2)
- O(5)–Sc(1)–Cl(2)
- Cl(1)–Sc(1)–Cl(1i)
- Sc(1)–Cl(1)
- 98.11(4)
- Cl(1)–Sc(1)–Cl(1i)
- 2.4403(6)
- Sc(1)–O(4)
- 2.177(2)
- Sc(1)–Cl(1)
- 2.4403(6)
- Sc(1)–O(5)
- 2.142(1)
- Sc(1)–Cl(2)
- 2.4267(8)
- C–O
- 1.419(3)–1.446(3)
- C–C
- 1.441(3)–1.484(4)
- O(4)–Sc(1)–O(5)
- 81.89(4)
- O(4)–Sc(1)–Cl(1)
- 88.14(2)
- O(5)–Sc(1)–O(5i)
- 163.78(8)
- O(4)–Sc(1)–Cl(2)
- 180.00
- Cl(1)–Sc(1)–Cl(2)
- 91.86(2)
- O(5)–Sc(1)–Cl(1)
- 89.79(5)
- Cl(1)–Sc(1)–Cl(1i)
- 176.27(3)
- O(5)–Sc(1)–Cl(2)
- 98.11(4)
- Table 5 Selected bond lengths (Å) and angles (°) for [Sc(NO3)3(H2O)2]·(12-crown-4)20
- 2.268(1)
- Sc(1)–O(3)
- 2.252(2)
- Sc(1)–O(6)
- Sc(1)–O(3)
- Sc(1)–O(4)
- 2.105(2)
- Sc(1)–O(3)
- 2.201(2)
- 1.417(3)–1.444(3)
- C–O
- 2.252(2)
- C–C
- C–O
- Sc(1)–O(4)
- 1.492(3)–1.505(4)
- C–O
- 2.201(2)
- 56.98(7)
- O(1)–Sc(1)–O(1i)
- 2.252(2)
- O(3)–Sc(1)–O(4)
- O(1)–Sc(1)–O(1i)
- Sc(1)–O(4)
- 57.58(5)
- O(1)–Sc(1)–O(1i)
- 2.201(2)
- Sc(1)–O(1)
- 2.252(2)
- Sc(1)–O(4)
- 2.201(2)
- Sc(1)–O(3)
- 2.268(1)
- Sc(1)–O(6)
- 2.105(2)
- C–O
- 1.417(3)–1.444(3)
- C–C
- 1.492(3)–1.505(4)
- O(1)–Sc(1)–O(1i)
- 56.98(7)
- O(3)–Sc(1)–O(4)
- 57.58(5)
- O(6)–Sc(1)–O(6i)
- 153.64(9)
- Table 6 Selected bond lengths (Å) and angles (°) for [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-40
- 2.366(2)
- Sc(1)–O(2)
- 2.261(2)
- Sc(1)–O(7)
- Sc(1)–O(2)
- Sc(1)–O(6)
- 2.050(2)
- Sc(1)–O(2)
- 2.101(2)
- 2.128(2)
- Sc(1)–O(4)
- 2.261(2)
- Sc(1)–O(7i)
- Sc(1)–O(4)
- Sc(1)–O(6)
- 2.064(2)
- Sc(1)–O(4)
- 2.101(2)
- 2.186(2)
- Sc(1)–O(5)
- 2.261(2)
- Sc(1)⋯Sc(1i)
- Sc(1)–O(5)
- Sc(1)–O(6)
- 3.296(1)
- Sc(1)–O(5)
- 2.101(2)
- 1.511(4)
- C(1)–C(2)
- 2.261(2)
- C(3)–C(4)
- C(1)–C(2)
- Sc(1)–O(6)
- 1.488(4)
- C(1)–C(2)
- 2.101(2)
- 1.431(3)–1.435(3)
- C–O
- 2.261(2)
- NoValue
- C–O
- Sc(1)–O(6)
- NoValue
- C–O
- 2.101(2)
- 55.23(6)
- O(1)–Sc(1)–O(2)
- 2.261(2)
- O(7)–Sc(1)–O(7i)
- O(1)–Sc(1)–O(2)
- Sc(1)–O(6)
- 73.54(7)
- O(1)–Sc(1)–O(2)
- 2.101(2)
- Sc(1)–O(1)
- 2.261(2)
- Sc(1)–O(6)
- 2.101(2)
- Sc(1)–O(2)
- 2.366(2)
- Sc(1)–O(7)
- 2.050(2)
- Sc(1)–O(4)
- 2.128(2)
- Sc(1)–O(7i)
- 2.064(2)
- Sc(1)–O(5)
- 2.186(2)
- Sc(1)⋯Sc(1i)
- 3.296(1)
- C(1)–C(2)
- 1.511(4)
- C(3)–C(4)
- 1.488(4)
- C–O
- 1.431(3)–1.435(3)
- O(1)–Sc(1)–O(2)
- 55.23(6)
- O(7)–Sc(1)–O(7i)
- 73.54(7)
- Sc(1)–O(7)–Sc(1i)
- 106.46(7)
- Table 7 Selected bond lengths (Å) and angles (°) for [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)30
- 2.345(2)
- Sc(1)–O(2)
- 2.346(2)
- Sc(2)–O(10)
- Sc(1)–O(2)
- Sc(2)–O(9)
- 2.033(2)
- Sc(1)–O(2)
- 2.089(2)
- 2.298(3)
- Sc(1)–O(4)
- 2.346(2)
- Sc(2)–O(11)
- Sc(1)–O(4)
- Sc(2)–O(9)
- 2.155(3)
- Sc(1)–O(4)
- 2.089(2)
- 2.337(2)
- Sc(1)–O(5)
- 2.346(2)
- Sc(2)–O(12)
- Sc(1)–O(5)
- Sc(2)–O(9)
- 2.174(2)
- Sc(1)–O(5)
- 2.089(2)
- 2.170(2)
- Sc(1)–O(7)
- 2.346(2)
- Sc(2)–O(13)
- Sc(1)–O(7)
- Sc(2)–O(9)
- 2.352(2)
- Sc(1)–O(7)
- 2.089(2)
- 2.153(3)
- Sc(1)–O(8)
- 2.346(2)
- Sc(2)–O(14)
- Sc(1)–O(8)
- Sc(2)–O(9)
- 2.291(2)
- Sc(1)–O(8)
- 2.089(2)
- 2.039(2)
- Sc(1)–O(9)
- 2.346(2)
- Sc(2)–O(16)
- Sc(1)–O(9)
- Sc(2)–O(9)
- 2.341(2)
- Sc(1)–O(9)
- 2.089(2)
- 2.087(2)
- Sc(1)–O(10)
- 2.346(2)
- Sc(2)–O(17)
- Sc(1)–O(10)
- Sc(2)–O(9)
- 2.355(2)
- Sc(1)–O(10)
- 2.089(2)
- 3.324(1)
- Sc(1)⋯Sc(2)
- 2.346(2)
- NoValue
- Sc(1)⋯Sc(2)
- Sc(2)–O(9)
- NoValue
- Sc(1)⋯Sc(2)
- 2.089(2)
- 2.465(3)
- Na(1)–O(19)
- 2.346(2)
- Na(1)–O(23)
- Na(1)–O(19)
- Sc(2)–O(9)
- 2.499(3)
- Na(1)–O(19)
- 2.089(2)
- 2.490(3)
- Na(1)–O(20)
- 2.346(2)
- Na(1)–O(24)
- Na(1)–O(20)
- Sc(2)–O(9)
- 2.449(3)
- Na(1)–O(20)
- 2.089(2)
- 2.503(3)
- Na(1)–O(21)
- 2.346(2)
- Na(1)–O(25)
- Na(1)–O(21)
- Sc(2)–O(9)
- 2.449(3)
- Na(1)–O(21)
- 2.089(2)
- 2.431(3)
- Na(1)–O(22)
- 2.346(2)
- Na(1)–O(26)
- Na(1)–O(22)
- Sc(2)–O(9)
- 2.475(3)
- Na(1)–O(22)
- 2.089(2)
- 1.416(4)–1.436(4)
- C–O
- 2.346(2)
- C–C
- C–O
- Sc(2)–O(9)
- 1.502(5)–1.518(5)
- C–O
- 2.089(2)
- 54.38(9)
- O(1)–Sc(1)–O(2)
- 2.346(2)
- O(13)–Sc(2)–O(14)
- O(1)–Sc(1)–O(2)
- Sc(2)–O(9)
- 54.89(9)
- O(1)–Sc(1)–O(2)
- 2.089(2)
- 55.02(9)
- O(4)–Sc(1)–O(5)
- 2.346(2)
- O(16)–Sc(2)–O(17)
- O(4)–Sc(1)–O(5)
- Sc(2)–O(9)
- 54.28(9)
- O(4)–Sc(1)–O(5)
- 2.089(2)
- 72.52(9)
- O(9)–Sc(1)–O(10)
- 2.346(2)
- O(9)–Sc(2)–O(10)
- O(9)–Sc(1)–O(10)
- Sc(2)–O(9)
- 72.61(9)
- O(9)–Sc(1)–O(10)
- 2.089(2)
- 107.3(1)
- Sc(1)–O(9)–Sc(2)
- 2.346(2)
- Sc(1)–O(10)–Sc(2)
- Sc(1)–O(9)–Sc(2)
- Sc(2)–O(9)
- 107.6(1)
- Sc(1)–O(9)–Sc(2)
- 2.089(2)
- Sc(1)–O(1)
- 2.346(2)
- Sc(2)–O(9)
- 2.089(2)
- Sc(1)–O(2)
- 2.345(2)
- Sc(2)–O(10)
- 2.033(2)
- Sc(1)–O(4)
- 2.298(3)
- Sc(2)–O(11)
- 2.155(3)
- Sc(1)–O(5)
- 2.337(2)
- Sc(2)–O(12)
- 2.174(2)
- Sc(1)–O(7)
- 2.170(2)
- Sc(2)–O(13)
- 2.352(2)
- Sc(1)–O(8)
- 2.153(3)
- Sc(2)–O(14)
- 2.291(2)
- Sc(1)–O(9)
- 2.039(2)
- Sc(2)–O(16)
- 2.341(2)
- Sc(1)–O(10)
- 2.087(2)
- Sc(2)–O(17)
- 2.355(2)
- Sc(1)⋯Sc(2)
- 3.324(1)
- Na(1)–O(19)
- 2.465(3)
- Na(1)–O(23)
- 2.499(3)
- Na(1)–O(20)
- 2.490(3)
- Na(1)–O(24)
- 2.449(3)
- Na(1)–O(21)
- 2.503(3)
- Na(1)–O(25)
- 2.449(3)
- Na(1)–O(22)
- 2.431(3)
- Na(1)–O(26)
- 2.475(3)
- C–O
- 1.416(4)–1.436(4)
- C–C
- 1.502(5)–1.518(5)
- O(1)–Sc(1)–O(2)
- 54.38(9)
- O(13)–Sc(2)–O(14)
- 54.89(9)
- O(4)–Sc(1)–O(5)
- 55.02(9)
- O(16)–Sc(2)–O(17)
- 54.28(9)
- O(9)–Sc(1)–O(10)
- 72.52(9)
- O(9)–Sc(2)–O(10)
- 72.61(9)
- Sc(1)–O(9)–Sc(2)
- 107.3(1)
- Sc(1)–O(10)–Sc(2)
- 107.6(1)
- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f1.gif
The structure of the cation in [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN showing the atom labelling scheme. Displacement ellipsoids are drawn at the 40% probability level and the H atoms are omitted for clarity.- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f2.gif
The structure of the cation involving Sc(1) in [ScCl2(18-crown-6][FeCl4] showing the atom labelling scheme. The Sc(2) species is similar, differing in the conformation at C(7) and O(4). Displacement ellipsoids are drawn at the 50% probability level and the H atoms are omitted for clarity.- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f3.gif
The structure of [ScCl3(H2O)3]·18-crown-6 (a) shows the Sc(1) group with the atom labelling scheme and the 2-fold symmetry lying along O(4), Sc(1) and Cl(2). Displacement ellipsoids are drawn at the 50% probability level; (b) view down the a direction showing the chain of O–H⋯O bonds between the Sc groups and the crown parallel to the c direction. The H-bonding is indicated by single lines and the H atoms are omitted for clarity.- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f4.gif
The structure of [Sc(NO3)2(H2O)4](NO3)·15-crown-5 showing the O–H⋯O H-bonded chain between the Sc cation and the crown (H-bonds as dotted lines) lying parallel to the b direction. A partial atom labelling scheme is shown with O(10)–O(13) being coordinated water molecules. O(17A)
(not labelled) is in a disordered part of the crown and is not involved in H-bonding. H atoms are omitted for clarity.- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f5.gif
The structure of [Sc(NO3)3(H2O)2]·(12-crown-4)2
(a) shows the Sc(1) group with the atom labelling scheme and the 2-fold symmetry in the c direction passing through Sc(1), N(1) and O(2). Displacement ellipsoids are drawn at the 50% probability level; (b) view down the c direction showing the O–H⋯O bonds (thin lines) between O(6i) of the Sc group and the crown. (Symmetry operation: i = 1/2+x, 1/2−y, −z).- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f6.gif
The structure of [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4 (a) shows the centrosymmetric cation with the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level; (b) shows part of the 2-dimensional sheet formed by the O–H⋯O H-bonding (indicated by dotted lines).- http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/Articleimage/2003/DT/b210458j/b210458j-f7.gif
The structure of [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3 showing the scandium dimer with the atom labelling scheme. Displacement ellipsoids are drawn at the 50% probability level and the H atoms are omitted for clarity.- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- Sc
- C
- Cl
- N
- Sb
systemAutoTableParserOrthorhombic- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Crystal systemPbca- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Space groupFalse- 8.0
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
8Z- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Crystal system- 4064.0
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
4064F(000)- 1051.68
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
1051.68M- [ScCl2(18-crown-6)][FeCl4]
- Sc
- Cl
- Fe
systemAutoTableParserOrthorhombic- [ScCl2(18-crown-6)][FeCl4]
Crystal systemPna21- [ScCl2(18-crown-6)][FeCl4]
Space groupFalse- 8.0
- [ScCl2(18-crown-6)][FeCl4]
8Z- [ScCl2(18-crown-6)][FeCl4]
Crystal system- 2344.0
- [ScCl2(18-crown-6)][FeCl4]
2344F(000)- 577.82
- [ScCl2(18-crown-6)][FeCl4]
577.82M- [ScCl3(H2O)3]·18-crown-6
- H
- O
- Sc
- Cl
systemAutoTableParserOrthorhombic- [ScCl3(H2O)3]·18-crown-6
Crystal systemPbcn- [ScCl3(H2O)3]·18-crown-6
Space groupFalse- 4.0
- [ScCl3(H2O)3]·18-crown-6
4Z- [ScCl3(H2O)3]·18-crown-6
Crystal system- 984.0
- [ScCl3(H2O)3]·18-crown-6
984F(000)- 469.67
- [ScCl3(H2O)3]·18-crown-6
469.67M- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- O
- Sc
- H
- N
- Na
systemAutoTableParserTriclinic- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Crystal systemP1̄- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Space groupFalse- 2.0
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
2Z- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Crystal system- 976.0
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
976F(000)- 935.5
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
935.50M- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- H
- O
- Sc
- N
systemAutoTableParserTriclinic- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Crystal systemP1̄- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Space groupFalse- 1.0
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
1Z- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Crystal system- 340.0
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
340F(000)- 656.28
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
656.28M- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- H
- O
- Sc
- N
systemAutoTableParserOrthorhombic- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Crystal systemP21212- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Space groupFalse- 2.0
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
2Z- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Crystal system- 652.0
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
652F(000)- 619.44
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
619.44M- [ScCl2(18-crown-6)][FeCl4]
- Sc
- Cl
- Fe
Space groupAutoTableParserOrthorhombic- [ScCl2(18-crown-6)][FeCl4]
Crystal systemPna21- [ScCl2(18-crown-6)][FeCl4]
Space groupFalse- 8.0
- [ScCl2(18-crown-6)][FeCl4]
8Z- [ScCl2(18-crown-6)][FeCl4]
Space group- 2344.0
- [ScCl2(18-crown-6)][FeCl4]
2344F(000)- 577.82
- [ScCl2(18-crown-6)][FeCl4]
577.82M- [ScCl3(H2O)3]·18-crown-6
- H
- O
- Sc
- Cl
Space groupAutoTableParserOrthorhombic- [ScCl3(H2O)3]·18-crown-6
Crystal systemPbcn- [ScCl3(H2O)3]·18-crown-6
Space groupFalse- 4.0
- [ScCl3(H2O)3]·18-crown-6
4Z- [ScCl3(H2O)3]·18-crown-6
Space group- 984.0
- [ScCl3(H2O)3]·18-crown-6
984F(000)- 469.67
- [ScCl3(H2O)3]·18-crown-6
469.67M- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- O
- Sc
- H
- N
- Na
Space groupAutoTableParserTriclinic- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Crystal systemP1̄- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Space groupFalse- 2.0
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
2Z- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
Space group- 976.0
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
976F(000)- 935.5
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
935.50M- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- H
- O
- Sc
- N
Space groupAutoTableParserTriclinic- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Crystal systemP1̄- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Space groupFalse- 1.0
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
1Z- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
Space group- 340.0
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
340F(000)- 656.28
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
656.28M- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- H
- O
- Sc
- N
Space groupAutoTableParserOrthorhombic- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Crystal systemP21212- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Space groupFalse- 2.0
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
2Z- [Sc(NO3)3(H2O)2]·(12-crown-4)2
Space group- 652.0
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
652F(000)- 619.44
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
619.44M- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- Sc
- C
- Cl
- N
- Sb
Space groupAutoTableParserOrthorhombic- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Crystal systemPbca- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Space groupFalse- 8.0
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
8Z- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
Space group- 4064.0
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
4064F(000)- 1051.68
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
1051.68M 10.1039/b210458j- 12-crown-4
- 12-crown-4
- ScCl2(18-crown-6)][FeCl4
- crown ether–Ti
- 15-crown-5
- [ScCl4(MeCN)2]−
- ScCl3(H2O)3
- O
- thioether-scandium(III)
- crown ether
- Sc(NO3)3·5H2O
- C12H30N3O18Sc
- 1H
- Lewis acid
- hydrogen
- ethers
- d6-acetone
- P4O10
- [ScCl3(H2O)3]·18-crown-6
- O(4)
- H2Oligands
- [ScCl(15-crown-5)(MeCN)][SbCl6]2
- O(N)
- FeCl3
- 18-crown-6
- 1H
- hydrogen
- lanthanide
- scandium
- [Sc(12-crown-4)2][SbCl6][Sb2Cl8(MeCN)2]·2MeCN
- O
- [Sc(H2O)2(NO3)3]·15-crown-5
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- 12-crown-4
- O–H
- crown
- [Sc2(OH)2(H2O)6(NO3)2](NO3)2·12-crown-4
- H
- H
- H2O
- nitrogen
- scandium
- [Sc(H2O)2(NO3)3]·(12-crown-4)2
- MeCN
- chloride
- O
- Cl−
- crown O
- MeCN
- O(4)
- MeCN
- ScCl3·6H2O
- ScCl3(thf)3
- Cl
- crown
- ScCl3(H2O)3
- MeCN
- [ScCl3(H2O)3]2·12-crown-4
- ScCl3·6H2O
- Me2CO
- 3222br, 1631m, 1300m, 1262w, 1140m, 1101m
- chloride
- Na+
- NaOH
- crown
- crown
- 15-crown-5
- H
- ScCl3·6H2O
- scandium
- ν2(NO3)
- [15]aneS2O3
- crown ether
- scandium
- [ScCl2(12-crown-4)]+
- chlorines
- [ScCl2(18-crown-6)]SbCl6
- O–H
- crown
- 1H
- [CuCl4]2−
- oxygen
- crown
- SbCl5
- SbCl5
- ScCl2(18-crown-6][FeCl4
- ScCl2(18-crown-6)][FeCl4
- C10H32Cl6O11Sc2
- ethers
- ethers
- [ScCl3(H2O)3]·18-crown-6
- scandium
- scandium nitrate
- ethanol
- OH
- ScCl3-R3PO
- ethanol
- d6-acetone
- [ScCl(18-crown-6)]2+
- 1H
- hydrogen
- scandium chloride/crown ether
- O
- ethanol
- Me2CO
- MeCN
- crown
- Cl
- H
- MeCN
- [ScCl(15-crown-5)(MeCN)][SbCl6]2·MeCN
- ether oxygens
- d6-acetone
- 12-crown-4
- thia-oxa-crown 1,4-dithia-7,10,13-trioxacyclopentadecane
- transition metals
- 15-crown-5
- crown
- H
- SbCl5
- Sc(NO3)3·5H2O
- scandium chloride
- MeCN
- [Sc(H2O)4(NO3)2]NO3·15-crown-5
- [ScCl2(18-crown-6)]FeCl4
- O(N)
- nitrate
- scandium
- 12-crown-4
- MeCN
- 15-crown-5
- ethanol
- scandium
- Sc(NO3)3(OPPh3)2
- d6-acetone
- [ScCl2(15-crown-5)]+
- nitrate
- crown
- oxygen
- nitrate
- Sc(NO3)3·5H2O
- ScCl3(thf)3
- Sc(NO3)3·5H2O
- H
- 12-crown-4)·[Sc(NO3)3(H2O)2]·(12-crown-4
- d(Sc–O)
- MeCN
- 18-crown-6
- O(11)
- crown
- H
- d3-MeCN
- sodium
- H
- C10H28N3O18Sc
- NaOH
- ethers
- O
- MeCN
- [ScCl2(18-crown-6)]FeCl4
- crown
- crown
- [ScCl2(18-crown-6)]SbCl6
- MeCN
- 1H
- 15-crown-5
- H
- H
- ethers
- 15-crown-5
- 12-crown-4
- EtOH
- scandium nitrate
- ScCl2O5’
- scandium
- scandium
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- [ScCl4(MeCN)2]−
- O–H
- EtOH
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- ethanol
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- 12-crown-4
- Sc(NO3)3·5H2O
- ScCl3(thf)3
- [ScCl3(H2O)3]2·15-crown-5
- crown
- ScCl3(thf)3
- scandium-aquo-hydroxo-nitrato
- [ScCl3(H2O)3]2·15-crown-5
- [ScCl2([15]aneS2O3)]FeCl4
- [Sc(H2O)2(NO3)3]·(12-crown-4)2
- scandium
- H
- H
- scandium nitrate
- 18-crown-6
- SbCl5
- CH2O
- hydrogen
- hydroxy
- [Sc(H2O)4(NO3)2]NO3·15-crown-5
- scandium
- 18-crown-6
- 18-crown-6
- ScCl3(thf)3
- crown
- H
- 18-crown-6
- crown
- scandium
- Sc(1)
- crown ethers
- ScCl2([15]aneS2O3)][FeCl4
- scandium
- scandium
- scandium
- NO3ligand
- O(17A)
- ethanol
- Mo
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- SbCl3
- 1H
- ethanol
- bidentate nitrate
- 1H
- [Sc(12-crown-4)2]3+
- ScCl2(18-crown-6)][FeCl4
- 15-crown-5
- FeCl3
- nitrate
- H
- SbCl5
- [Sc(12-crown-4)2]3+
- FeCl3
- [ScCl3(H2O)3]·18-crown-6
- hydrated scandium nitrate
- 7-coordinate trans pentagonal bipyramidal scandium
- ScCl3·6H2O
- O–H
- [Sc(NO3)3(H2O)2]·(12-crown-4)2
- H
- H
- N
- C12H30Cl3O9Sc
- O–H
- H
- NO3ligands
- O(13)
- ethers
- O–H
- 12-crown-4
- 12-crown-4
- 12-crown-4
- 12-crown-4
- thia-oxa-crown [15]aneS2O3
- oxygen
- ScCl3(thf)3
- MeCN
- 1H
- 12-crown-4
- ethanol
- H
- nitrogen
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- nitrogen
- crown ether
- d6-acetone
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- N(1)
- Sc(III)
- CH2S
- Sc–Cl
- ScCl3(thf)3
- MeCN
- LiCl
- ScCl2(18-crown-6)][FeCl4
- H
- [ScCl(15-crown-5)(MeCN)]2+
- scandium-aquo-nitrato
- O
- crown
- ethanol
- scandium chloride-crown
- scandium
- MeCN
- [Sc(18-crown-6)]3+
- EtOH
- ScCl4(MeCN)2
- O H
- [Sc(12-crown-4)2]3+cation
- C12H36Cl6O12Sc2
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- chloride
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- nitrate
- 1H
- crown
- MeCN
- C10H28N3O18Sc
- ethanol
- TiCl4(18-crown-6)
- O
- crown
- 1H
- crown
- scandium nitrate
- H
- Sc(1)
- Sc3+
- 18-crown-6
- [ScCl2(18-crown-6)]SbCl6
- ethers
- O(4)
- MeCN
- MeCN
- pentagonal bipyramidal
- crown
- NO3ligands
- O(N)
- ScCl3(thf)3
- nitrate
- H
- [ScCl2(15-crown-5)]+
- SbCl5
- 18-crown-6
- chloride
- O
- O
- ethanol
- Lewis acid
- MeCN
- SbCl5
- crown ether oxygen
- 18-crown-6
- hydrogen
- FeCl3
- H
- ScCl2(15-crown-5)][SbCl6
- crown ether
- H
- crown ether
- 9-coordinate lanthanide
- Hydrogen
- d3-MeCN
- crown ether
- H
- [SbCl6]−
- H
- H
- nitrogen
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- H2O
- CD2Cl2
- hydrogen
- [15]aneS2O3
- mer-[ScCl3(H2O)3]·18-crown-6
- DPX400
- MeCN
- [ScCl3(H2O)3]·18-crown-6
- nitrogen
- O
- routine.Methylene hydrogen
- ScCl3(thf)3
- Sc(1)
- ethers
- ScCl3·6H2O
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- nitrate
- crown ethers
- crown
- FeCl3
- scandium nitrate
- ethanol
- ScCl2(18-crown-6)][FeCl4
- crown
- H
- hydrate
- [ScCl3(H2O)3]2·18-crown-6
- Sc3+
- [Sc(H2O)2(NO3)3]·(12-crown-4)2
- crown O
- O
- MeCN
- Sc(NO3)3(H2O)2
- ScCl3(thf)3
- 1H
- scandium
- H
- 1H
- Sc(1)
- scandium chloride
- crown
- bidentate nitrate
- O H
- ethanol
- Sc(NO3)3·5H2O
- ethanol
- C12H24Cl6FeO6Sc
- MeCN
- Me2CO
- MeCN
- hydrogen
- [Sc(NO3)2(H2O)4](NO3)·15-crown-5
- [Sc(NO3)2(H2O)4](NO3)·15-crown-5
- [Sc(NO)3(H2O)2]·(12-crown-4)2
- [Sc(H2O)3(NO3)3]·18-crown-6
- scandium
- [ScCl(15-crown-5)(MeCN)][SbCl6]2·MeCN
- H
- ethanol
- SbCl5
- OH
- Sc2(NO3)4(H2O)4(OH)2
- FeCl3
- ScCl3(thf)3
- H
- [Sb(18-crown-6·SbCl5)(MeCN)x]3+
- Na/benzophenone
- FeCl3
- crown ether
- [ScCl3(H2O)3]2·18-crown-6
- H
- [ScCl3(thf)3]/18-crown-6/SbCl5/MeCN
- Scandium(III)
- [Sc2(H2O)6(OH)2(NO3)2](NO3)2·12-crown-4
- ScCl3(MeCN)3
- ScCl3·6H2O
- ScCl3/18-crown-6
- TiCl4(18-crown-6)
- 15-crown-5
- chloride
- ScCl3·6H2O
- 12-crown-4
- Sc(NO3)3·5H2O
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- ScCl2([15]aneS2O3)][FeCl4
- [Sc(H2O)6]3+
- scandium
- H
- 1H
- crown
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- H
- crown ether
- O⋯O
- [Sc(12-crown-4)2][SbCl6]2
- [Sc(H2O)3(NO3)3]·18-crown-6
- H
- H
- d(O⋯O)
- O
- 15-crown-5
- [Sc(H2O)4(NO3)2]NO3·15-crown-5
- SbCl5
- nitrate
- crown
- crown
- [Sc(H2O)2(NO3)3]·(12-crown-4)2
- scandium
- dichloro
- scandium(III)
- OH
- EtOH
- 1H
- 15-crown-5
- dihydroxy-bridged Sc dimer
- H2O
- 15-crown-5
- 18-crown-6
- scandium
- O(2)
- [ScCl2(12-crown-4)(MeCN)]SbCl6
- MeCN
- thioether
- SbCl5
- O
- Cl(2)
- graphite
- 12-crown-4
- H
- MeCN
- FeCl3
- H
- [ScCl(MeCN)(15-crown-5)][SbCl6]2·MeCN
- H
- H
- H
- 18-crown-6
- ScCl3·6H2O
- ScCl3(MeCN)3
- [ScCl(15-crown-5)(MeCN)][SbCl6]2
- O
- H(O)
- crown
- SbCl5
- crown
- crown
- scandium
- scandium
- H
- bidentate NO3
- scandium
- [ScCl3(H2O)3]·18-crown-6
- OH
- 18-crown-6
- [ScCl3(H2O)3]·18-crown-6
- ethanol
- MeCN
- [ScCl3(H2O)3]n·(crown)
- ethers
- lanthanide
- scandium(III)
- μ-O
- OH
- d6-acetone
- crown ether
- [ScCl2(12-crown-4)(MeCN)]SbCl6
- crown ether
- scandium
- crown
- ethanol
- H
- Sc–O
- MeCN
- H
- MeCN
- H
- Na
- ScCl3(H2O)3
- oxygens
- ethanol
- 18-crown-6
- Lewis acids
- ScCl3(thf)3
- [ScCl3(H2O)3]·18-crown-6
- C8H28Cl6O10Sc2
- ethanol
- d6-acetone
- SbCl5
- d6-acetone
- ScCl3
- scandium
- [Sc2(NO3)4(H2O)4(OH)2][Na(12-crown-4)2](NO3)·(H2O)3
- Cl
- crown
- H
- H
- 18-crown-6
- [Sc(H2O)4(NO3)2]NO3·15-crown-5
- scandium
- ethers
- pentagonal bipyramidal
- H
- H
- H
- Sc(NO3)3·5H2O
- (18-crown-6)Cl3Ti–O–TiCl3(18-crown-6)
- [Sc2(NO3)2(H2O)6(OH)2](NO3)2·12-crown-4
- MeCN
- ScCl3·6H2O
- nitrate
- O H
- scandium
- SbCl5
- 1H
- SbCl5
- ScCl3(thf)3
- [Sc2(NO3)4(H2O)4(OH)2]·[Na(12-crown-4)2]NO3·(H2O)3
- FeCl3
- [Sc(NO3)3(H2O)3]·18-crown-6
- 12-crown-4
- 18-crown-6
- Na+
- [Sc(NO3)2(H2O)4](NO3)·(C10H20O5)
- thioether
- ethanol
- ScCl3(H2O)3
- O–Sc–O
- MeCN
- ethanol
- 1H
- ScCl3(thf)3
- CD2Cl2
- H
- MeCN
- 1H
- [ScCl3(H2O)3]2·12-crown-4
- [ScCl2(15-crown-5)]+
- scandium
- crown
5Primary and secondary coordination of crown ethers to scandium(III). Synthesis, properties and structures of the reaction products of ScCl3(thf)3, ScCl3·6H2O and Sc(NO3)3·5H2O with crown ethers0- Michael D. Brown
- William Levason
- David C. Murray
- Michael C. Popham
- Gillian Reid
- Michael Webster
- Michael D. Brown
- William Levason
- David C. Murray
- Michael C. Popham
- Gillian Reid
- Michael Webster
Dalton Transactionshttp://pubs.rsc.org/en/Content/ArticlePDF/2003/DT/B210458Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2003/DT/B210458J865857Royal Society of Chemistry- 1916
- monochromator
- NN
- (
- -LRB-
- Table
- NN
Tablemonochromator - 2218
- NMR
- NN
- resonance
- NN
- (
- -LRB-
- δ
- NN
δNMR resonance - 4845
- [Sc(NO3)3(OPPh3)2]
- NN
- (
- -LRB-
- δ
- NN
δ[Sc(NO3)3(OPPh3)2] - 2219
- °
- NN
- (
- -LRB-
- Table
- NN
Table° - 2521
- -
- HYPH
- coordinate
- NN
- (
- -LRB-
- Table
- NN
Table- coordinate 2003-02-24- 18-crown-6crown
- 15-crown-5crown
- 0.11 ) 2868 unique reflections ( 1726 withRint